The role of hydrogen bonds involving the metal atom in protonation of polyhydrides of molybdenum and tungsten of MH4(dppe)2
β Scribed by E.S. Shubina; A.N. Krylov; N.V. Belkova; L.M. Epstein; A.P. Borisov; V.D. Mahaev
- Publisher
- Elsevier Science
- Year
- 1995
- Tongue
- English
- Weight
- 224 KB
- Volume
- 493
- Category
- Article
- ISSN
- 0022-328X
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## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a βFull Textβ option. The original article is trackable v
Ethylenediamine (en) solutions of [P 7 M(CO) 3 ] 3Β± (M = Cr, W) react with weak acids to give [HP 7 M(CO) 3 ] 2Β± ions where M = Cr (4 a) and W (4 b) in high yields. Competition studies with known acids revealed a pK a range for 4 b in DMSO of 17.9 to 22.6. The [P 7 M(CO) 3 ] 3Β± complexes also react