✦ LIBER ✦

The role of HNO in the H2NO reaction

✍ Scribed by Kenneth A. Wilde

Publisher: Elsevier Science
Year: 1969
Tongue: English
Weight: 743 KB
Volume: 13
Category: Article
ISSN: 0010-2180
DOI: 10.1016/0010-2180(69)90048-0

No coin nor oath required. For personal study only.

✦ Synopsis

The previously available overall rate data for the H2-NO reaction have l~.en re-examined in the light of new data on elementary reaction steps, with numerical integration of the governing differential equations. The reaction HNO + NO = N20 + OH has been found to be an importanL slow step. The calculated overall initial rate is approximately second order in NO and one-half order in H2, in agreement with most of the data. The overall rate is more or less proportional to the rate of the HNO + NO reaction, which has a rate constant of 10123 ±0-3 exp (-26000 +_ 5 000) cm3/mole sec [800=-106OC).

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