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The role of free radicals in the low-temperature crosslinking (vulcanization) of rubber

✍ Scribed by B.A. Dogadkin; E.N. Beliaeva


Book ID
118355001
Publisher
Elsevier Science
Year
1960
Weight
539 KB
Volume
1
Category
Article
ISSN
0032-3950

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The aim of the present work is to study the free-radical kinetics of PDMS rubber crosslinking in the presence of 2,2,6,6-tetramethylpiperidinyloxyl (TEMPO) nitroxide. For this purpose a new method based on the relationship between the kinetics of the macro-radicals coupling [R cc (t)] was derived fr