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The role of dioxygen in hydrosilylation of alkenes catalyzed by ruthenium phosphine complexes

✍ Scribed by Jacek Guliński; Brian R. James; Bogdan Marciniec


Publisher
Elsevier Science
Year
1995
Tongue
English
Weight
674 KB
Volume
499
Category
Article
ISSN
0022-328X

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📜 SIMILAR VOLUMES


On the existence of dioxygen adducts of
✍ B.R. James; L.D. Markham; A.D. Rattray; D.K.W. Wang 📂 Article 📅 1976 🏛 Elsevier Science 🌐 English ⚖ 168 KB

The reported [3] I: 1 O2 absorption by RuC12-(AsPh& must be due to oxidation of 2 mol of coordinated arsine in complexes such as those listed above. The so-called 880 cm-' peroxide band is attributable to VA-, and the paramagnetism and esr signals (assigned to a Ru"'-O; moiety) are likely due to Ru(