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The role of complex formation in the polymerization of unsaturated polyesters by a cationic mechanism in the presence of SnCl4 and TiCl4

✍ Scribed by T.E. Lipatova; R.P. Khoroshko; S.S. Gusev

Book ID: 118358449
Publisher: Elsevier Science
Year: 1968
Weight: 643 KB
Volume: 10
Category: Article
ISSN: 0032-3950
DOI: 10.1016/0032-3950(68)90249-9

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## Abstract The polymerization of styrene was studied by using a bifunctional initiator, 1,4‐bis(1‐chloroethyl)benzene (1). It was demonstrated that living polymerization can be achieved in the styrene/1/SnCl~4~ system in chloroform at −15°C in the presence of 2,6‐di‐__tert__‐butylpyridine. The num