The role of charge transfer interactions in the decomposition of organic peroxides—I: Benzoyl peroxide-amine systems in non-restricted fluid media

The role of charge transfer interactions

The role of charge transfer interactions in the decomposition of organic peroxides—II: Spontaneous and amine-induced decomposition of dibenzoyl peroxide in partially restricted media

✍ S.E. Morsi; A.B. Zaki; M.A. El-Khyami 📂 Article 📅 1977 🏛 Elsevier Science 🌐 English ⚖ 229 KB

The kinetics of unimolecular spontaneous and bimolecular amine induced decomposition of dibenzoyl peroxide (DBP) in partially restricted polymer media was studied. Initial reaction rates were calculated and used for evaluation of kinetic parameters. Activation energies were calculated: for spontaneo