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The role of carboxylic acids on a Na2WO4/H2WO4-based biphasic homogeneous alkene epoxidation, using H2O2 as oxidant

✍ Scribed by Palanisamy Uma Maheswari; Xiaohua Tang; Ronald Hage; Patrick Gamez; Jan Reedijk


Publisher
Elsevier Science
Year
2006
Tongue
English
Weight
422 KB
Volume
258
Category
Article
ISSN
1381-1169

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Selective epoxidation of unsaturated (meth)acrylic esters by various classical epoxidizing agents was investigated. It is shown that high selectivity and good yields are obtained by using the system Hz02 (20%) -Na2W04 under phase transfer catalysis. Under these conditions, the rigourous control of t