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The Role of Bulk Oxide Ion in the Catalytic Oxidation Reaction over Metal Oxide Catalyst

✍ Scribed by Yoshihiko Moro-oka; Wataru Ueda; Kang-Hee Lee

Publisher
John Wiley and Sons
Year
2003
Weight
52 KB
Volume
34
Category
Article
ISSN
0931-7597

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✍ Jack J. Lin; Robert T. Holmes; Kevin M. Smith πŸ“‚ Article πŸ“… 1998 πŸ› John Wiley and Sons 🌐 English βš– 128 KB πŸ‘ 2 views

Previous literature work has assumed that the metal ion in metal-assisted a,c-biladiene cyclizations serves as a chelator as well as an oxidant. New results suggest that the metal is not of primary importance in aligning the tetrapyrroles into the proper cyclic conformation prior to cyclization. Tho