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The Role of 1,N6-Ethenoadenosine Triphosphate and 1,N6-Ethenoadenosine Monophosphate in Firefly Luminescence

✍ Scribed by M. Deluca, N. J. Leonard, B. J. Gates and W. D. McElroy

Book ID
123651420
Publisher
National Academy of Sciences
Year
1973
Tongue
English
Weight
526 KB
Volume
70
Category
Article
ISSN
0027-8424

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Protonation and quaternization of 1, N6-
Protonation and quaternization of 1, N6-ethenoadenosine: What are the species responsible for the fluorescence of 1, N6-ethenoadenosine?
✍ Yasuo Inoue; Takao Kuramochi; Keiichi Imakubo 📂 Article 📅 1979 🏛 Wiley (John Wiley & Sons) 🌐 English ⚖ 1022 KB

## Abstract Methylation of 1,__N__^6^‐ethenoadenosine (εAdo) gives a mixture of N1‐ and N9‐quaternized methyl‐3‐β‐D‐ribofuranosylimidazo[2,1‐__i__] purinium salts (m^1^εAdo^+^ and m^9^εAdo^+^, respectively). The ratio of the two forms of the protonated εAdo [H^1^εAdo^+^]/[H^9^εAdo^+^] has been esti