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The ritter reaction of poly(acrylonitrile) with tert.-butyl alcohol

✍ Scribed by V. Janout; P. Čefelín

Book ID
107753728
Publisher
Elsevier Science
Year
1980
Tongue
English
Weight
360 KB
Volume
16
Category
Article
ISSN
0014-3057

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Reactions of radicals with polymers—III.
Reactions of radicals with polymers—III. Abstraction reactions of methyl and tert. butyl radicals with poly(p-tert. butyl styrene)
✍ N.A. Weir; M. Rujimethabhas 📂 Article 📅 1985 🏛 Elsevier Science 🌐 English ⚖ 506 KB

The kinetics of H abstraction by methyl and tert.butyl radicals from poly(p-tert.butyl styrene) (PTL3) films (5 × 10 3 mm thick) have been investigated at 298 K, both radicals being produced from the polymer by its exposure to short-wave u.v. radiation (2 = 254 nm) at pressures < 10 -4 Pa. Different