The resonance Raman spectra of intermediate-spin ferrous porphyrin

✍ Scribed by Teizo Kitagawa; Junji Teraoka

• Publisher: Elsevier Science
• Year: 1979
• Tongue: English
• Weight: 318 KB
• Volume: 63
• Category: Article
• ISSN: 0009-2614
• DOI: 10.1016/0009-2614(79)80685-5

✦ Synopsis

The resonance Raman and absorption spectra of unligatcd ferrous ocractb~ lporplwrin t&*fOEP)] and Its adduct tlith I"Velm or TtIF acre observed. The resommcc Ramaa spectrum of Te"(OEP) in CIi~Cl2 dispbq cd cbamctcristic features of iron porph>rio &ith three d, electron+. susgesting 3Ee 3~ the intermediate-spin (S = 1) sound st.tte_ fe'*t.OIZP) in TIfF e\hibited the ferrous high spin feature like Fe2*(OEP) (_-McIm) in Cff=Ctz-'i