The REMPI spectroscopy of Cl2; a bound-free-bound route to the 1g(1D2) ion-pair state
β Scribed by M.N. Al-Kahali; R.J. Donovan; K.P. Lawley; Z. Min; T. Ridley
- Book ID
- 107943044
- Publisher
- Elsevier Science
- Year
- 1996
- Tongue
- English
- Weight
- 757 KB
- Volume
- 208
- Category
- Article
- ISSN
- 0301-0104
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π SIMILAR VOLUMES
Rotational contours of the (2+ 1) REMPI spectra of iodine due to resonance excitation to the [ ZlIs,z]c5d; lg Rydberg state have been recorded at room temperature. Rotational parameters, &, were estimated from the band-head structure and used to derive the band origin by spectral simulations. T.= 59
The \(0_{g}^{+}\left({ }^{1} D\right)\) ion-pair state of \(\mathrm{I}_{2}\) has been analyzed by optical-optical double-resonance using the \(0_{g}^{+}\left({ }^{1} D\right)-B^{3} \Pi\left(0_{u}^{+}\right)-X^{1} \Sigma_{g}^{+}\)photoexcitation sequence. The analysis of the 374 transitions in the \(
We have analyzed the 1 u ( 1 D) and 2 u ( 1 D) ion-pair states of I 2 by perturbation-facilitated optical-optical double resonance using the B 3 (0 + u ) βΌ c1 g mixing state as an intermediate. The double-resonance spectra exhibited the strong vibrational progression to the 1 u ( 1 D) state in accor
The optical-optical double-resonance spectroscopy is applied to study the ion-pair states of \(\mathrm{Cl}_{2}\) correlating to \(\mathrm{Cl}^{-}\left({ }^{1} S\right)+\mathrm{Cl}^{+}\left({ }^{3} P_{2}\right)\). In the \((1+2)\) photoexcitation sequence, we gain access to the \(0_{u}^{+}\left({ }^{