✦ LIBER ✦

The relaxation of local modes of vibrationally-hot molecules in cold environments: anharmonicity and condensed phase effects

✍ Scribed by A.H. Zewail; D.J. Diestler

Publisher: Elsevier Science
Year: 1979
Tongue: English
Weight: 433 KB
Volume: 65
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(79)80120-7

No coin nor oath required. For personal study only.

✦ Synopsis

WC provide ;1 description of the relaxation of vibmtionalI_-hot molcculcs in cold emironmcnts. The motcc~te has rrriiw Cli local modes intcrxting with an inactire rcrcrroir of modes. It is shoan tIut the anJturnzonicir_r of these 10~~1 rnodr5 2nd the inrcrmolecular effects can conspire to m&e the relationship bewcen the hmxidth of the o\ertonc and the iJrrmtuokcuhr deca? time nonstmightfon%rd. especially zt high ener$es.