The relative significance of multiple pathways in peroxyoxalate chemiluminescence reactions
β Scribed by Ji Hoon Lee; Seung Yong Lee; Kang-Jin Kim
- Book ID
- 107710395
- Publisher
- Elsevier Science
- Year
- 1996
- Tongue
- English
- Weight
- 817 KB
- Volume
- 329
- Category
- Article
- ISSN
- 0003-2670
No coin nor oath required. For personal study only.
π SIMILAR VOLUMES
The peroxyoxalate system undergoes one of the most efficient chemiluminescence reactions and is the only one considered to involve an intermolecular chemically initiated electron exchange luminescence mechanism, with proven high efficiency. Several reactive intermediates have been proposed, which, u
A facde means of optumzmg solvent composltlons and reagent concentrations for the peroxyoxalate chemdununescence (PO-CL) detectlon of fluorescent compounds urlth bdem~2\_(3.6,9-tnoxadecyl~henyll oxalate (TDPO) and hydrogen pemde m hqmd chromatography (LC) was developed The reation tune course of CL
## Abstract The highβenergy intermediates generated in the reaction of bis(2,4,6βtrichlorophenyl)oxalate (TCPO) with H~2~O~2~ can excite electronically different fluorophores with a high quantum yield in organic solvents. We have previously applied this peroxyoxalate chemiluminescent reaction to th