The Relative Sign of J C 13 -C 13
β Scribed by Grant, David M.
- Book ID
- 126028856
- Publisher
- American Chemical Society
- Year
- 1967
- Tongue
- English
- Weight
- 295 KB
- Volume
- 89
- Category
- Article
- ISSN
- 0002-7863
No coin nor oath required. For personal study only.
π SIMILAR VOLUMES
## Abstract Analysis of the noise decoupled ^13^C spectra of doubly ^13^C labelled compounds where the two labelled carbons are identical, makes the determination of reltive signs of ^13^Cο£Ώ^13^C coupling constants possible in a very simple way. The involved carbon form AA'X or AA'B spin systems.
## Abstract Magnitudes and signs of ^13^Cο£Ώ^13^C coupling constants in compounds of the type Ph^13^CR^1^R^2^ο£Ώ^13^CR^1^R^2^Ph have been determined and the results are discussed in a broader context. Two types of coupling constants, __J__(Cβi, CβΞ±) and __J__(Cβi, CβΞ²), between aromatic carbon atoms an