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The Relative Sensitivity of Triphenylmethyl Chloride to Electrophiles and Nucleophiles in Benzene Solution

โœ Scribed by Hawthorne, M. F.; Cram, Donald J.


Book ID
126836367
Publisher
American Chemical Society
Year
1954
Tongue
English
Weight
754 KB
Volume
76
Category
Article
ISSN
0002-7863

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Relative rates of nucleophilic reactions
โœ Soili Jaarinen; Jukka Niiranen; Jouko Koskikallio ๐Ÿ“‚ Article ๐Ÿ“… 1985 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 325 KB

Benzyl chloride and benzyl acetate were photolyzed in 30% methanol-water mixtures (V/V) at 0ยฐC. The photolysis produces benzyl carbocations that react with nucleophiles. The reaction products were analyzed by gas chromatography or liquid chromatography. From the amounts of products the relative valu