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The relative reactivity of primary and secondary amino groups in aromatic amines

✍ Scribed by N.S. Kogarko; V.A. Topolkarayev; G.M. Trofimova; V.V. Ivanov; A.A. Berlin; D.D. Novikov; N.S. Yenikolopyan


Book ID
118965916
Publisher
Elsevier Science
Year
1978
Weight
454 KB
Volume
20
Category
Article
ISSN
0032-3950

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The kinetics of the reactions of primary and secondary amines with benzhydrylium ions and quinone methides in acetonitrile have been studied under pseudo-first-order conditions (high excess of amines) by UV/Vis spectrophotometry. Generally, the plots of k obs versus amine concentration were linear,