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The Relative Reactivities of Triphenylsilyllithium and Organometallic Compounds in Coupling with Halosilanes

โœ Scribed by Gilman, Henry.; Trepka, William J.; Wittenberg, Dietmar.


Book ID
126472786
Publisher
American Chemical Society
Year
1962
Tongue
English
Weight
570 KB
Volume
84
Category
Article
ISSN
0002-7863

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Treatment of 2-p.yridyl 2-thienyl sulfoxide with 2thienyllithium was found to give both 2-(2-pyri-dy1)thiophene 2 and 2,5-(di-2-pyridyl)thiophene 3. The reaction between 2-thienyllithium and thionyl chloride was found to give 2,2'-bithienyl 8, a coupling product, which is also formed by the reaction