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The relative and absolute configuration of clerocidin and its cometabolites

✍ Scribed by N.Rastrup Andersen; P.R. Rasmussen; C.P. Falshaw; T.J. King

Publisher
Elsevier Science
Year
1984
Tongue
French
Weight
247 KB
Volume
25
Category
Article
ISSN
0040-4039

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✦ Synopsis

The structures of clerocidin and five cometabolites have been established by chemical interconversion, spectral, and X-ray crystallographic methods. Fermentation of the fungus, Oidiodendron truncatum, produces clerocidin (PR 1350)land five cometabolites: PR 1389, m.p. 140-142'C, [dD + 40.6O (c, 0.23, MeOH) PR 1383, colourless oil, (ref. 1) PR 1421, m-p. 157-159"C, [dD + 69.8O (c, 0.53, MeOH) PR 1387, m-p. 214-216OC, 0.25, CHC13)

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