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The relationship between vibrational amplitudes and internuclear distances

✍ Scribed by V. S. Mastryukov; E. L. Osina; L. V. Vilkov; S. Cyvin

Publisher: SP MAIK Nauka/Interperiodica
Year: 1976
Tongue: English
Weight: 297 KB
Volume: 17
Category: Article
ISSN: 0022-4766
DOI: 10.1007/bf00748395

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## Abstract The AMO function of the hydrogen molecule ψ = ψ~c~ + η ψ~__i__~, where ψ~c~ is the covalent part and ψ~__i__~ the ionic part, is investigated for small internuclear distances __R__. We found η → −1 as R →,−1 as __R__ → 0, contrary to the intuitively expected limit η → 1. However, near _