Ethyl, propyl and butyl homologues of phenol have been chromatographed on layers of cellulose impregnated with simple amides (formamide, N-methylformamide and N,N-dimethylforrnamide) using hexane as the mobile phase. The plots of RM value vs. the logarithm of the concentration of the amide in the sl
β¦ LIBER β¦
The relationship between crystal structure and NMR relaxation in molecular solids with tert-butyl groups
β Scribed by Arnold L. Rheingold; Antonio G. DiPasquale; Peter A. Beckmann
- Book ID
- 108089021
- Publisher
- Elsevier Science
- Year
- 2008
- Tongue
- English
- Weight
- 522 KB
- Volume
- 345
- Category
- Article
- ISSN
- 0301-0104
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The X-ray crystal structures of 2,1l-bis(di-R-phosphinomethyl)benzo[c]phenanthrenes (R = Ph, t -Bu) are reported. Both ligands have the same conformation and the substitution of a Ph by a t -Bu group does not cause significant changes in the tetracyclic aromatic unit which shows the same distortions