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The relation of ring-proton chemical shifts to structure in chelated 2,4-pentanedionato complexes

✍ Scribed by David W Thompson


Publisher
Elsevier Science
Year
1969
Weight
202 KB
Volume
1
Category
Article
ISSN
0022-2364

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The olefinic phosphane P(C 7 H 7 ) 3 (5) behaves as a tetradentate tripod ligand in [RhCl{P(g 2 -C 7 H 7 ) 3 }] (6), using all 3 cyclohepta-2,4,6-trienyl substituents as g 2 -coordinating side-arms. Nucleophilic displacement of the one-electron chloro ligand by halides or pseudohalides to give [RhX{