The relation between structure and dehydration of K2MF5H2O compounds
✍ Scribed by Peter Bukovec; Nataša Bukovec
- Publisher
- Elsevier Science
- Year
- 1985
- Tongue
- English
- Weight
- 206 KB
- Volume
- 92
- Category
- Article
- ISSN
- 0040-6031
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The dehydration of TlB 5 O 6 (OH) 4 • 2H 2 O leads to a loss of water in one step, forming anhydrous TlB 5 O 8 , which is amorphous to X-ray diffraction. This can be explained by structural considerations; a decrease in oxygenated coordination of thallium ions occurs during the heating. TlB 5 O 8 cr
The crystal structure of hydrated sodium aluminate, \(\mathrm{NaAlO}_{2}\). \(5 / 4 \mathrm{H}_{2} \mathrm{O}\), has been determined \(a b\) initio from synchrotron powder diffraction data. The compound crystallizes in the acentric primitive tetragonal space group \(\bar{P} 2_{1} m\), with \(a=10.53