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The relation between collinear and 3-D dynamical calculations of reactive molecular collisions

โœ Scribed by R.B. Bernstein; R.D. Levine


Publisher
Elsevier Science
Year
1974
Tongue
English
Weight
702 KB
Volume
29
Category
Article
ISSN
0009-2614

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โœฆ Synopsis


Qne~important difference between the ;esult! of collinear and of full 3-D dynamical computations &es from, 1 the difftirence in the available volume in phase space (1-D versus 3-D) which cti be termed a "dimensionality-bias".

Correction for fhis phase space factor bows for a more realistic estimate of reaction cross sections, branching ratios r?nd Z&D product.enera distibutions from kollincaz cakulations.

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