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The Relation between Bond Lengths and Dissociation Energies of Carbon−Carbon Bonds

✍ Scribed by Zavitsas, Andreas A.


Book ID
120170765
Publisher
American Chemical Society
Year
2003
Tongue
English
Weight
38 KB
Volume
107
Category
Article
ISSN
1089-5639

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Using 25 accurately known bond-stretching force constants and bond lengths for 23 molecules, a relation of the form: F' = 37.3 r 5 35 has been obtained for carbon-nitrogen bonds. The root-mean-square deviation between the force constant values reported in the literature and those calculated from the