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The regio- and stereocontrolled ring opening of heteroarylglycidates with nitrogen nucleophiles

✍ Scribed by Benito Alcaide; Cristina Biurrun; Ana Martínez; Joaquín Plumet


Book ID
103401454
Publisher
Elsevier Science
Year
1995
Tongue
French
Weight
222 KB
Volume
36
Category
Article
ISSN
0040-4039

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A practical method for the synthesis of b-hydroxymercaptans has been successfully developed through the ring-opening of epoxides with organic dithiophosphorus acids 1. Highly regio-and stereoselective products, b-hydroxyalkyl dithiophosphates, which were transformed to the corresponding syntheticall