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The Reduction of Phosphorus and Antimony Chlorides by Trimethylarsine and Trimethylstibine 1

โœ Scribed by Holmes, Robert R.; Bertaut, Edgard F.

Book ID
126966444
Publisher
American Chemical Society
Year
1958
Tongue
English
Weight
430 KB
Volume
80
Category
Article
ISSN
0002-7863

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The polarographic hydrogen wave of hydrochloric acid in non-aqueous methanolic sohrtions shifts towards less negative potentials in presence of traces of triphenylphosphine, -arsine and -stibine. Tbe three additives exert a catalytic effect on the hydrogen-evolution reaction. This character has been