The reduction of oxygen has been examined in 1 M NaOH at 25Β°C with a fluid&d bed
The reduction of oxygen at a metallized membrane electrode
β Scribed by C. McCallum; D. Pletcher
- Publisher
- Elsevier Science
- Year
- 1975
- Tongue
- English
- Weight
- 329 KB
- Volume
- 20
- Category
- Article
- ISSN
- 0013-4686
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β¦ Synopsis
Metallized membrane electrodes have recently been incorporated into analytical devices for monitoring the oxygen content of atmospheres. This paper describes a simple model for this type of electrode structure and shows that it applies well to the conditions used in an analytical device. The diffusion coefficient for oxygen in PTFE is shown to be 1.1 + @l x lo-" m2 s-l.
π SIMILAR VOLUMES
The electrochemistry of four gases, hydrogen, nitric oxide, nitrogen dioxide and sulphur dioxide at metallized membrane electrodes is reported. It is shown that, as was the case with oxygen and carbon monoxide, it is possible by suitable choice of electrode potential, electrode metal and electrolyte
The steady-state reduction ofoxygen in O,-saturated 2 N H,SO, solution was obtalned at constant current on the front side of a Pt fo11 diaphragm before and after strong anodization of the back side. Strong anodization converts the Pt to a Pt-0 alloy. In all cases, the overvoltage for O2 reduction wa