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The reduction mechanism of the >CO group: Part 1. The electrochemical reduction of methyl isonicotinate in an aqueous medium

✍ Scribed by E. Laviron; R. Meunier-Prest; E. Mathieu

Publisher
Elsevier
Year
1994
Tongue
English
Weight
660 KB
Volume
371
Category
Article
ISSN
1572-6657

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The reduction mechanism of the >CO grou
The reduction mechanism of the >CO group —III. The electrochemical reduction of isonicotinic acid in an aqueous medium
✍ E. Mathieu; R. Meunier-Prest; E. Laviron 📂 Article 📅 1997 🏛 Elsevier Science 🌐 English ⚖ 501 KB

The electrochemical reduction of isonicotinic acid NRCOOH and its protonated from H+NRCOOH has been examined in an aqueous medium between Hc, = 0 and pH 6.7. As shown by cyclic voltammetry and polarography, a global 2e-, 2H+ reversible transfer is followed by two successive first-order chemical reac