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The redox switch/redox coupling hypothesis

✍ Scribed by Sebastián Cerdán; Tiago B. Rodrigues; Alejandra Sierra; Marina Benito; Luis L. Fonseca; Carla P. Fonseca; María L. García-Martín


Book ID
116764804
Publisher
Elsevier Science
Year
2006
Tongue
English
Weight
575 KB
Volume
48
Category
Article
ISSN
0197-0186

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Redox-switched crown ethers monocrown-bi
✍ Takahide Minami; Seiji Shinkai; Osamu Manabe 📂 Article 📅 1982 🏛 Elsevier Science 🌐 French ⚖ 205 KB

To give a redox-switch function to crown ethers, 4'-mercaptomonobenzo-15-crown-S(CrSH) and its oxidized dlsulflde form (CrSSCr) were synthesized. The solvent extraction proved that the ion affinity of CrSH 1s generally greater than that of CrSSCr.