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The redox behaviour of the cluster anion [Fe4N(CO)12]−. Electron transfer chain catalytic substitution reactions. Crystal structure of [Fe4N(CO)11PPh3)]−

✍ Scribed by Piero Zanello; Franco Laschi; Arnaldo Cinquantini; Roberto Della Pergola; Luigi Garlaschelli; Mario Cucco; Francesco Demartin; Trevor R. Spalding


Publisher
Elsevier Science
Year
1994
Tongue
English
Weight
773 KB
Volume
226
Category
Article
ISSN
0020-1693

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The hexacarbide clusters [H 6-n Ni 38 C 6 (CO) 42 ] n-(n = 3, 4, 5, found previously in [HNi 38 C 6 (CO) 42 ] 5-, and shows very close interatomic separations. Both [Ni 32 C 6 (CO) 36 ] 6-and [H 6- or 6) have been directly obtained from the reaction of [Ni 6 -(CO) 12 ] 2-with C 3 Cl 6 , whereas the