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The redox behaviour of ferrocene derivatives: III. Ferrocenylacyl complexes (η5-C5H5) Fe(η5-C5H4-COER3 E  C, Si or Ge; R  Me or Ph

✍ Scribed by Piero Zanello; Giuliana Opromolla; Luca Pardi; Keith H. Pannell; Hemant K. Sharma


Publisher
Elsevier Science
Year
1993
Tongue
English
Weight
314 KB
Volume
450
Category
Article
ISSN
0022-328X

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## Abstract The reaction of the vinylidene complexes [(C~5~H~5~)(CO)(NO)W=C=C(H)R] (10a: R = __t__Bu; 10b: R = Ph) with the arsaalkene __t__BuC(O)–As=C(NMe~2~)~2~ (11) afforded the novel η^2^‐1‐arsaallene complexes [η^2^‐{__t__BuC(O)–As=C=C(H)R}W(CO)(NO)C~5~H~5~] (13: R = __t__Bu; 15: R = Ph). Simi