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The Rearrangement of α-Silyl Ketones with Alkoxides

✍ Scribed by Brook, A. G.; Schwartz, N. V.


Book ID
126159495
Publisher
American Chemical Society
Year
1962
Tongue
English
Weight
584 KB
Volume
27
Category
Article
ISSN
0022-3263

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Syntheses of α, β-Epoxy Silyl Ketones
✍ Markus E. Scheller; W. Bernd Schweizer; Bruno Frei 📂 Article 📅 1989 🏛 John Wiley and Sons 🌐 German ⚖ 462 KB

The terms A, B, and C are used for the description of diastereoisomers, whose configurations were not assigned conclusively. ## ' ) Due to the low amounts of pure 5A + Bin our hands, the oxidation was not repeated with CrO,/pyridine, the reagent which would have led to a higher yield of 2. MHz):