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The rearrangement of some 2-substituted-4-bromo-2,5-dinitro-6-hydroxy-3,6-dimethylcyclohex-3-en-1-ones

✍ Scribed by P.A. Bates; M.J. Gray; M.P. Hartshorn; Huong Tuong Ing; K.E. Richards; W.T. Robinson


Publisher
Elsevier Science
Year
1981
Tongue
French
Weight
117 KB
Volume
22
Category
Article
ISSN
0040-4039

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## Abstract Dehydrochlorination of chlorinated 5‐hydroxy‐2‐oxabicyclo[3.2.0]heptan‐4‐ones, 3a‐c, which were obtained from the photo[2+2]cycloadditions between 4‐hydroxy‐3(2__H__)‐furanone 1 and chloroethylenes, with triethylamine gave 2‐ethenyl‐3(2__H__)‐furanones 4a,b or 2‐(2‐cyanoethyl)‐3(2__H__)