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The rearrangement of N-chloro-1-methyl-1-aminocyclopentane in the presence of alkyllithiums

✍ Scribed by LeRoy W. Haynes; Richard A. Amos

Book ID
112123049
Publisher
Journal of Heterocyclic Chemistry
Year
1973
Tongue
English
Weight
141 KB
Volume
10
Category
Article
ISSN
0022-152X

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The photochemical behaviour of 2-methyl-5-nitro-I H-imidazoles 1 in water-containing solutions has been studied. In a first reaction step, the photorearrangement of 1 yields 2-methyl-2-imidazoline-4,5-dione-4-oximes 2. Hydrolysis of 2 and subsequent elimination of water from a supposed intermediate