The standard potentials of the Ag/AgCl electrode in water-methylcellosolve mixtures have been determined at 25, 30,35,40 and 45Β°C. The values of E,,,' in each solvent is determined as a function of temperature. The plot of E,,,' against the reciprocal dielectric constant at 25Β°C indicates the existe
The real standard potential on the aqueous hydrogen scale of the silver/silver chloride electrode in methanol: the surface potential of methanol
β Scribed by Colin G. Barraclough; Antonio Borazio; Peter T. McTigue; Bruce Verity
- Publisher
- Elsevier Science
- Year
- 1988
- Weight
- 933 KB
- Volume
- 243
- Category
- Article
- ISSN
- 0022-0728
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π SIMILAR VOLUMES
The standard potentials of Ag-Agi3r electrode in eighteen dioxane +water solvent mixtures containing up to 90 wt y0 dioxane, have been evaluated from the emfmeasurements of the cell Pt, Ha (g, 1 atm): HBr (m), X % dioxane, Y "/, water: AgBr, Agat nine different temperatures in the range 15-55Β°C. The
We show through enhanced Raman scattering from chloride on silver at large positive metal charge that the Stark effect and bond perturbation play minor roles in the potential dependence of the spectra. The major influence on the intensity and frequency of these spectra can be explained by charges ln