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The reactivity of [Pt2(μ-S)2(PPh3)4] towards difunctional chloroacetamide alkylating agents: Formation of cyclized or bridged products

✍ Scribed by Oguejiofo T. Ujam; William Henderson; Brian K. Nicholson; Christopher M. Fitchett


Book ID
113642140
Publisher
Elsevier Science
Year
2011
Tongue
English
Weight
596 KB
Volume
375
Category
Article
ISSN
0020-1693

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✍ Siew Huay Chong; Antonius Tjindrawan; T.S.Andy Hor 📂 Article 📅 2003 🏛 Elsevier Science 🌐 English ⚖ 240 KB

Activity of [Pt 2 (-S) 2 (PPh 3 ) 4 ] (1) towards 1,4-dichlorobutane, 1,2-dichloroethane, ␣-␣ -dichloro-o-xylene and ␣-␣dichloro-m-xylene and the catalytic role of 1 in the syntheses of organosulfur materials was studied by in situ electrospray mass spectroscopy (ESMS). An intermediate, [Pt 2 (-SC 2