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The reactivity in the system CuCl-Si related to the activation of silicon in the Direct Synthesis

✍ Scribed by J. Acker; S. Köther; K.M. Lewis; K. Bohmhammel

Book ID
111611563
Publisher
Springer
Year
2003
Tongue
English
Weight
216 KB
Volume
2
Category
Article
ISSN
1569-0660

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Hydroxy esters are reduced by trimethoxysilane in the presence of a catalytic amount of lithium methoxide to yield diols, while for simple esters the alcohol exchange reaction takes place preferentially. Through the exchange reaction, lactones without a hydroxy group are reduced. Tosylimines are als