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The reactive states of ions: Octatrienes and dimethyl substituted cyclohexadienes

✍ Scribed by M. E. Rennekamp; M. K. Hoffman

Publisher: John Wiley and Sons
Year: 1975
Tongue: English
Weight: 528 KB
Volume: 10
Category: Article
ISSN: 1076-5174
DOI: 10.1002/oms.1210101205

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✦ Synopsis

Abstract

The principal decomposition routes of molecular ions of cis, cis, cis‐2,4,6‐octatriene, cis, cis, trans‐2,4,6‐octatriene, trans, cis, trans‐2,4,6‐octatriene, trans‐5,6‐dimethyl‐1,3‐cyclohexadiene and cis‐5,6‐dimethyl‐1,3‐cyclohexadiene were studied using ion kinetic spectroscopy. The loss of radicals from [M]^+^· appears to proceed via a ground state, while loss of a neutral molecule appears to involve either complete equilibration of structure within the system or both ground state and excited state pathways.

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