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The reactions of thiols and diphenyldisulfide with terminally substituted methylenecyclopropanes

✍ Scribed by Bo Xu; Yu Chen; Min Shi


Book ID
104250807
Publisher
Elsevier Science
Year
2002
Tongue
French
Weight
61 KB
Volume
43
Category
Article
ISSN
0040-4039

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✦ Synopsis


In the reactions of thiols with terminally substituted methylenecyclopropanes, we found that the Markovnikov adducts were produced exclusively along with cyclopropyl ring-opened products via a radical reaction mechanism. The substituent effects and the reaction with diphenyldisulfide were also examined.


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ChemInform Abstract: The Reactions of Th
✍ Bo Xu; Yu Chen; Min Shi πŸ“‚ Article πŸ“… 2010 πŸ› John Wiley and Sons βš– 28 KB πŸ‘ 1 views

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