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The Reactions of the Hydroxymethyl Radical with 1,3-dimethyluracil and 1,3-dimethylthymine

โœ Scribed by Schuchmann, Heinz-Peter ;Wagner, Rita ;von Sonntag, Clemens

Book ID
120659206
Publisher
Informa UK (Taylor & Francis)
Year
1986
Tongue
English
Weight
857 KB
Volume
50
Category
Article
ISSN
0020-7616

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Stereochemistry of reaction products of
Stereochemistry of reaction products of 1,3-dimethylthymine epoxide with amines
โœ Takashi Harayama; Reiko Yanada; Tooru Taga; Fumio Yoneda ๐Ÿ“‚ Article ๐Ÿ“… 1985 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 221 KB

Reaction of 1,3\_dimethylthymine epoxide with amines afforded cis and trans adducts, stereostructures of which were elucidated and treatment of trans adduct with boron trifluoride etherate afforded cis adduct; mechanism for the isomerization is presented. Much attention has focused on the oxidations