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The reactions of methyl radicals with acetone, diethyl ketone, and di-tert.-butyl peroxide

✍ Scribed by Pritchard, G. O. ;Pritchard, H. O. ;Trotman-Dickenson, A. F.

Book ID
111686916
Publisher
The Royal Society of Chemistry
Year
1954
Weight
294 KB
Category
Article
ISSN
0368-1769

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Reactions of radicals with polymersβ€”III.
Reactions of radicals with polymersβ€”III. Abstraction reactions of methyl and tert. butyl radicals with poly(p-tert. butyl styrene)
✍ N.A. Weir; M. Rujimethabhas πŸ“‚ Article πŸ“… 1985 πŸ› Elsevier Science 🌐 English βš– 506 KB

The kinetics of H abstraction by methyl and tert.butyl radicals from poly(p-tert.butyl styrene) (PTL3) films (5 Γ— 10 3 mm thick) have been investigated at 298 K, both radicals being produced from the polymer by its exposure to short-wave u.v. radiation (2 = 254 nm) at pressures < 10 -4 Pa. Different