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The reactions of metastable [C5 H10 O]+˙ ions with the oxygen on the second carbon

✍ Scribed by David J. McAdoo; Charles E. Hudson; Fred W. McLafferty; Terry E. Parks

Publisher
John Wiley and Sons
Year
1984
Tongue
English
Weight
944 KB
Volume
19
Category
Article
ISSN
1076-5174

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The isomerizations preceding the metastable decompositions in the mass spectrometer of a number of [C,H,,O]+' ions with the oxygen on the third carbon are characterized utilizing deuterium labeling. Hydrogens are transferred in these ions by three-, five-and six-membered ring rearrangements, with pr

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## Abstract The structures of the C~4~H~7~O^+^ and C~3~H~6~O^+·^ dissociation products from selected C~5~H~10~O^+·^ isomers with the oxygen on the first, second and third carbons were determined. The first product is CH~3~C(OH)CHCH~2~^+^ and the second is CH~3~C(OH^+^)CH~2~⋅ and CH~3~⋅CHCHOH^+^ in