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The reactions of dimethyl 2,5-bis(diazo)-3,4-dikentoadipate with aromatic and heteroaromatic compounds

✍ Scribed by C.W. Bird; C.K. Wong; D.Y. Wong; F.L.K. Koh


Publisher
Elsevier Science
Year
1976
Tongue
French
Weight
611 KB
Volume
32
Category
Article
ISSN
0040-4020

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Dimethyl diazomalonate (4) and thiobenzophenone (2a) do not react in toluene even after warming to 50". After addition of catalytic amounts of Rh,(OAc),, a smooth reaction under N, evolution afforded a mixture of thiiranedicarboxylate 5 and (diphenylmethy1idene)malonate 6 (Scheme 2 ) . A reaction me