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The reactions of alkyltrimethylphosphinenickel complexes with isocyanides and alkynes

✍ Scribed by Manfred Bochmann; Ian Hawkins; Martin P. Sloan

Publisher
Elsevier Science
Year
1987
Tongue
English
Weight
604 KB
Volume
332
Category
Article
ISSN
0022-328X

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## Abstract Cyclopentadienyl–ruthenium half‐sandwich complexes with η^2^‐bound alkyne ligands have been suggested as catalytic intermediates in the early stages of Ru‐catalyzed reactions with alkynes. We show that electronically unsaturated complexes of the formula [RuCl(Cp^)(η^2^‐RC≡CR′)] can be s