The reaction of XeF2 with trialkylvinylstannanes: Scope and some mechanistic observations
β Scribed by Marcus A. Tius; Joel K. Kawakami
- Publisher
- Elsevier Science
- Year
- 1995
- Tongue
- French
- Weight
- 880 KB
- Volume
- 51
- Category
- Article
- ISSN
- 0040-4020
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The reaction of alkoxycarbonylmethylentriphenylphosphonium ylides 1 with alkyl propynoates 2 in dichlormethane proceeds via [2+2]cycloaddition rather than Michael addition, to lead to stabilised phosphonium ylides. In the course of our investigations into the reactivity of acetylendicarboxilic acid
The rapid, gas phase equilibrium addition of HO 2 radicals to CH 2 O to form the peroxy radical HOCH 2 OO β’ is in agreement with the known thermochemistry of these species. The recent study of the similar addition of HO 2 β’ to ketones shows no significant reaction, which is again in agreement with k