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The reaction of vinylmagnesium chloride with hindered ketones

โœ Scribed by Watanabe, S; Suga, K; Suematsu, Y; Suzuki, T


Book ID
121196383
Publisher
Commonwealth Scientific and Industrial Research Organisation Publishing
Year
1968
Tongue
English
Weight
243 KB
Volume
21
Category
Article
ISSN
0004-9425

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Irradiation of g-allqrlbenzophenones (I) results in formation of photoenols (II), which revert to the parent ketones in the dark.\* 2,5-Dimethylaaetophenone also gives a aorrespending photoenoi, but is slowly aonverted into presumably a pinacol. 3 It appeared interesting to examine photochemical beh