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The Reaction of Trityl Salts with 2-Methyltetrahydrofuran and with Tetrahydrofuran

โœ Scribed by Dreyfuss, M. P.; Westfahl, J. C.; Dreyfuss, P.


Book ID
126418550
Publisher
American Chemical Society
Year
1968
Tongue
English
Weight
514 KB
Volume
1
Category
Article
ISSN
0024-9297

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Synthesis and reactions of poly-tetrahyd
โœ Y. Tezuka; E.J. Goethals ๐Ÿ“‚ Article ๐Ÿ“… 1982 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 412 KB

The bulk polymerization of tetrahydrofuran (THF) intiated by methyl triflate or triflic anhydride leads to poly-THF's of polydispersity < 1.2 and possessing one or two oxonium chain ends, if the conversion is kept below 15}~. Reaction of these "living" polymers with an N-substituted azetidine leads