Reaction of Tungsten Hexacarbonyl with A
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Priv.-Doz. Dr. W. Beck; Dipl.-Chem. H. S. Smedal
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Article
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1966
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John Wiley and Sons
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English
β 137 KB
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Tungsten hexacarbonyl reacts with alkali or tetraalkylammonium halides or pseudohalides MIX (X = halogen or NCS) with elimination of one CO ligand, giving compounds of the type MI[W(CO),X] 121. However, tetraethylammonium azide [31 and W(CO)6 (molar ratio 1 : 15) in diethylene glycol dimethyl ether