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The reaction of triphenylphosphine with arylbromonitromethanes. Formation of arylnitriloxides.

โœ Scribed by E. Coutouli-Argyropoulou

Publisher
Elsevier Science
Year
1984
Tongue
French
Weight
110 KB
Volume
25
Category
Article
ISSN
0040-4039

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The triphenylphosphine deoxygenation of the polyperoxides, poly(styrene peroxide), poly(methyl methacrylate peroxide), and poly( a-methylstyrene peroxide) proceed via the phosphorane intermediates, which in the presence of moisture hydrolyze to give the respective diols. At higher temperatures and u